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"Alkylation"

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"Alkylation"

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Synonyms:
Replacement, Exchange, Alteration, Adjustment, Change, Variation, Adaptation, Revision, Alteration, Adjustment, Change, Shift, Metamorphosis, Transition, Changeover, Adaptation, Shift, Changeover, Transition, Alteration

A process in which an alkyl group is substituted or added to a compound. The alkyl group may be transferred as an alkyl carbocation, a free radical, a carbanion, or a carbene. Alkylating agents are reagents for effecting alkylation. Alkyl groups can also be removed in a process known as dealkylation.

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Merriam-Webster Online Dictionary
alkylation (noun)
the act or process of introducing one or more groups into a compound (as to increase octane number in a motor fuel) - alkyl
Alkylation (Wikipedia)

Alkylation is a chemical reaction that entails transfer of an alkyl group. The alkyl group may be transferred as an alkyl carbocation, a free radical, a carbanion, or a carbene (or their equivalents). Alkylating agents are reagents for effecting alkylation. Alkyl groups can also be removed in a process known as dealkylation. Alkylating agents are often classified according to their nucleophilic or electrophilic character. In oil refining contexts, alkylation refers to a particular alkylation of isobutane with olefins. For upgrading of petroleum, alkylation produces a premium blending stock for gasoline. In medicine, alkylation of DNA is used in chemotherapy to damage the DNA of cancer cells. Alkylation is accomplished with the class of drugs called alkylating antineoplastic agents.

Typical route for alkylation of benzene with ethylene and ZSM-5 as a heterogeneous catalyst
Alkylation (Wiktionary)

English

Etymology

From alkyl +‎ -ation.

Noun

alkylation (plural alkylations)

  1. (organic chemistry) Any reaction in which an alkyl group is added to a molecule; used in the production of high-octane petroleum fuels.

Derived terms

Related terms

  • alkylate
  • alkylated

Translations

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Alkylation

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